1.Lesson overview
- 3.4 Covalent bonding and coordinate (dative covalent) bonding
- 3.7 Dot-and-cross diagrams
- 3B Covalent bonding
- 1.3 Bonding (International AS)
- 1.8 Valence Electrons and Ionic Compounds
- 2.1 Types of Chemical Bonds
- 2.3 Structure of Ionic Solids
- 2.4 Structure of Metals and Alloys
- 2.5 Lewis Diagrams
- 2.6 Resonance and Formal Charge
- 2.7 VSEPR and Hybridization
- 2.2 Intramolecular Force and Potential Energy
- Describe a covalent bond as the electrostatic attraction between a shared electron pair and the nuclei of the bonded atoms, arising from orbital overlap.
- Construct accurate dot-and-cross or Lewis diagrams for covalent molecules and ions, showing lone pairs, charges and all valence electrons.
- Relate bond order to bond length and bond strength in covalent species.
- Represent the relationship between potential energy and internuclear distance, and relate the minimum to bond length and bond strength.
- Define a coordinate bond as donation of a lone pair by one atom and represent its formation in species such as ammonium.
- Use physical evidence, including melting point and electrical conductivity, to distinguish covalent substances from ionic or metallic substances.
Covalent bonding is best understood as an electrostatic attraction created by shared electron density, not as atoms simply touching. The orbital model explains why bonds have direction and strength, while coordinate bonding shows that a shared pair can originate from one atom without becoming a different kind of bond.
Move from orbital overlap to ordinary shared pairs, multiple bonds and dot-and-cross representations. Then examine coordinate bonds, bond order and bond properties, using evidence from structure and physical behaviour to distinguish covalent substances.
2.Key language and ideas
- Covalent bond
- Strong electrostatic attraction between two nuclei and a shared pair of electrons.
- Sigma bond,
- A covalent bond formed by head-on overlap of orbitals along the line joining two nuclei.
- Pi bond,
- A covalent bond formed by sideways overlap of parallel orbitals.
- Coordinate bond
- A covalent bond in which both electrons in the shared pair were donated by the same atom.
- Lone pair
- A pair of outer-shell electrons not used in covalent bonding.
- Bond enthalpy
- The enthalpy change needed to break one mole of a specified covalent bond in gaseous molecules.
3.Explain covalent bonding through orbital overlap
When atomic orbitals overlap, electron density lies between two nuclei. Attraction of both positive nuclei to this shared negative density holds the atoms together. A covalent bond is directional because the electron density is concentrated in a particular region of space.
A single bond is normally one bond. A double bond contains one and one bond; a triple bond contains one and two bonds. The weaker, exposed component makes multiple bonds especially important in organic reactivity.
4.A coordinate bond has a distinct origin, not distinct fate
A covalent bond is a shared pair of electrons. In a coordinate (dative) bond, both electrons in the newly shared pair originate from one donor species and enter an empty acceptor orbital. Once formed, the bond is not automatically weaker or chemically distinguishable solely because of its origin. Lewis structures help account for valence electrons and formal charges, but multiple valid resonance contributors may be needed where electrons are delocalised.
6.Relate bond order to bond length and strength
For the same pair of atoms, a higher bond order usually means more electron density between the nuclei, a shorter bond and a larger bond enthalpy. Thus a carbon-carbon triple bond is shorter and stronger than a carbon-carbon double bond, which is shorter and stronger than a carbon-carbon single bond.
These comparisons are valid only when the atoms being compared are the same. A bond's polarity and environment also influence its length and strength, so avoid treating one numerical bond-energy value as universal outside the stated molecule.
A potential-energy curve gives the same idea a visual form. As two atoms approach, attraction lowers potential energy until a minimum is reached at the equilibrium bond length. Bringing them closer than this creates strong repulsion, while separating them to a very large distance requires energy equal to the bond dissociation energy. A deeper minimum represents a stronger bond; its horizontal position gives the bond length.
7.Recognise coordinate bonding as electron-pair donation
A coordinate bond forms when a lone-pair donor supplies both electrons to an electron-deficient acceptor. For example, ammonia donates a lone pair to to form . Once formed, the coordinate bond is equivalent to the other N–H covalent bonds in the ion.
Coordinate bonding also explains dimeric aluminium chloride, in which chlorine lone pairs bridge between electron-deficient aluminium centres. In an arrow representation, draw the arrow from the atom with the lone pair to the atom or ion that accepts it.
8.Use evidence to identify covalent substances
Simple covalent molecules usually have low melting and boiling temperatures because only intermolecular attractions are overcome on melting or boiling; the strong covalent bonds within each molecule remain intact. They usually do not conduct electricity because they contain no mobile ions or delocalised electrons.
Giant covalent structures are different: covalent bonds extend throughout the solid, so they can have very high melting temperatures. Always identify whether a question concerns bonds within particles or forces between particles; confusing the two produces weak property explanations.
| Species | Key bonding feature |
|---|---|
| One shared pair; one bond. | |
| One and one bond. | |
| One and two bonds. | |
| Four N–H covalent bonds; one originated as a coordinate bond. |
9.Build covalent structures from electron accounting
A Lewis or dot-and-cross diagram is a bookkeeping model: count the valence electrons, place shared pairs between bonded atoms, then place remaining electrons as lone pairs. The drawing is only acceptable when every atom has the required electron count—or when an expanded octet or odd-electron species is explicitly allowed by the structure being discussed.
Orbital language adds a three-dimensional explanation. A sigma bond comes from direct overlap along the internuclear axis and permits rotation if no other bond prevents it. A pi bond comes from sideways overlap of parallel p orbitals; it is weaker than a sigma bond and restricts rotation because the p orbitals must remain aligned. A double bond therefore contains one sigma and one pi bond, while a triple bond contains one sigma and two pi bonds.
10.Worked example 1: Construct a dot-and-cross account for carbon dioxide
Describe the bonding and electron arrangement in .
- 1Carbon has four outer electrons and each oxygen has six, giving 16 outer electrons in total.
- 2Place carbon between the two oxygen atoms and form two shared pairs with each oxygen.
- 3Each C–O bond is a double bond: one and one bond.
- 4Each oxygen retains two lone pairs; carbon has no lone pairs in this representation.
11.Worked example 2: Explain formation of ammonium
Explain how forms from ammonia and a proton.
- 1Ammonia has a lone pair on nitrogen.
- 2The proton is electron deficient and accepts that lone pair.
- 3Nitrogen donates both electrons to form a coordinate covalent bond to hydrogen.
- 4The product has an overall +1 charge because the proton adds positive charge without adding an electron.
12.Worked example 3: Explain the bonding in NH₄⁺ formed when ammonia reacts with hydrogen chloride gas.
Explain the bonding in NH₄⁺ formed when ammonia reacts with hydrogen chloride gas.
- 1NH₃ contains three N–H covalent bonds and one lone pair on nitrogen.
- 2HCl transfers a proton, H⁺, to the lone pair on nitrogen; the chloride ion is the counter-ion.
- 3The lone pair forms a coordinate bond between N and H⁺, producing NH₄⁺.
- 4Once formed, all four N–H bonds are equivalent in the ion; the coordinate origin is a formation history, not a different final bond type.
13.Extended worked case: apply and evaluate
Explain formation of from and .
- 1
Nitrogen in has a lone pair; has no electron to contribute.
- 2
Nitrogen donates its lone pair into a bond with the proton, forming a fourth N–H bond.
- 3
The product has four N–H bonds and overall charge , represented by .
Do not draw one N–H bond as permanently special in the ammonium ion; the four bonds are equivalent in its tetrahedral structure.
14.Using physical evidence to infer bonding
Melting behaviour, conductivity and solubility provide evidence about structure. No one observation proves a model on its own, so compare a pattern of properties against the predictions for molecular, ionic, metallic and giant covalent materials.
- 1SelectStage 1Choose samples with contrasting known structures and record predicted conductivity and relative melting behaviour.
- 2ObserveStage 2Test conductivity where safe and inspect provided melting-point or boiling-point data rather than trying to heat unknown substances.
- 3InferStage 3State which particles are mobile and which attractions must be overcome, then identify the most consistent structure.
15.Connections, patterns and applications
16.Exam method: build a covalent representation accurately
Electron bookkeeping before drawing prevents missing lone pairs, incorrect charges and impossible valences.
- 1CountStage 1Add the outer electrons, adjusting for any ionic charge.
- 2ConnectStage 2Place the likely central atom and make shared pairs to give an appropriate outer shell.
- 3CheckStage 3Count electrons again, add lone pairs and charges, then identify , or coordinate bonds if asked.
17.Common misconceptions
- Calling a coordinate bond a different force after it has formed.
- Forgetting that a double bond contains one bond as well as one bond.
- Explaining a low boiling temperature by weak covalent bonds rather than weak forces between molecules.
18.Exam focus and retrieval
- In a dot-and-cross diagram, distinguish electron origins and show brackets around charged species.
- Use electron-pair donor and acceptor when explaining coordinate bonding.
- Specify whether a property depends on intramolecular bonds or intermolecular forces.
- 1How many bonds are in ?
- 2Which atom donates the shared pair in ammonium formation?
- 3Why are simple molecular substances usually non-conductors?
19.Summary
- Covalent bonds arise from attraction between nuclei and shared electron pairs.
- Multiple bonds contain one bond plus one or more bonds.
- Coordinate bonds form by donation of a lone pair and become ordinary covalent bonds once formed.
- Property explanations must distinguish covalent bonds from intermolecular forces.
- Construct and interpret dot-and-cross diagrams, orbital-overlap models, sigma and pi bonds, hybridisation, and coordinate bonds.
20.Curriculum alignment and applied reasoning
This extension turns the lesson into an exam-ready sequence: identify the evidence, apply the mechanism or calculation, then state a qualified conclusion. Core outcomes revisited here include: Describe a covalent bond as the electrostatic attraction between a shared electron pair and the nuclei of the bonded atoms, arising from orbital overlap.; Construct accurate dot-and-cross or Lewis diagrams for covalent molecules and ions, showing lone pairs, charges and all valence electrons.; Relate bond order to bond length and bond strength in covalent species..
| Course | Mapped focus in this lesson |
|---|---|
| Cambridge International A Level Chemistry 9701 | 3.4 Covalent bonding and coordinate (dative covalent) bonding 3.7 Dot-and-cross diagrams |
| Edexcel IAL Chemistry | 3B Covalent bonding |
| AQA International A-level Chemistry | 1.3 Bonding (International AS) |
| AP Chemistry | 1.8 Valence Electrons and Ionic Compounds 2.1 Types of Chemical Bonds 2.3 Structure of Ionic Solids 2.4 Structure of Metals and Alloys 2.5 Lewis Diagrams 2.6 Resonance and Formal Charge 2.7 VSEPR and Hybridization 2.2 Intramolecular Force and Potential Energy |
Scenario: Explain the formation of ammonium from ammonia and a proton using a displayed equation, then state why the coordinate bond is not permanently different from the other N–H bonds.
Worked reasoning: A lone pair on nitrogen is donated to H⁺:
Worked reasoning: . Once formed, the bonding electron density is shared and the four N–H bonds are equivalent in the ion; the arrow describes the origin of the shared pair.
Exam-quality communication: Show the donor lone pair and acceptor with an empty orbital/positive ion; avoid saying H⁺ supplies electrons.
- Name the observation, quantity, structure or variable before interpreting it.
- Show the causal step or calculation route; do not jump from data to a conclusion.
- State a limitation, condition or comparison whenever the evidence cannot justify an absolute claim.