May/June 2026 Paper 42

2026 · 9 questions · 56 parts · 100 marks

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5(a)Electrode Potentials Cell Free EnergyEasy2 marks
Define standard electrode potential, , including a description of standard conditions.
Definition
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Standard conditions
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5(b)(i)Electrode Potentials Cell Free EnergyMedium3 marks
Table 5.1 shows the standard electrode potentials for three redox systems.
redox systemelectrode reactionE / V ⦵⦵
1Fe + e Fe+0.77
2NO– + 10H + 8e NH+ + 3HO+0.87
3Zn + 2e Zn–0.76
Use the information in Table 5.1 to write equations for two reactions that are feasible. Explain why these reactions are feasible.
Two equations
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Explanation
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5(b)(ii)Electrode Potentials Cell Free EnergyMedium1 mark
Suggest why the feasible reactions in 5(b)(i) may not take place under standard conditions.

Answer

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5(b)(iii)Electrode Potentials Cell Free EnergyHard3 marks
An electrochemical cell is set up to measure for redox system 2 in Table 5.1 (NO + 10H + 8e NH + 3HO, ).
Complete Figure 5.1 to show a labelled diagram of this electrochemical cell. Include all necessary substances and relevant pieces of apparatus needed to measure . It is not necessary to state the conditions used.
Diagram to annotate
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Draw with the mouse or a finger.
5(c)Electrode Potentials Cell Free EnergyMedium2 marks
A different electrochemical cell is set up. The cell reaction for this electrochemical cell is shown.
Calculate the standard cell potential, , for this cell reaction.