May/June 2026 Paper 43

2026 · 9 questions · 63 parts · 100 marks

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2(a)(i)Ph Ionic Product WaterEasy1 mark
Define pH mathematically.
2(a)(ii)Ph Ionic Product WaterEasy1 mark
Define mathematically.

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2(b)(i)Weak Acids Bases BuffersEasy1 mark
Solution A is 100 cm of an aqueous solution of 0.105 mol dm butanoic acid, CHCHCHCOOH. A has pH 2.90 at 298 K.
Calculate the concentration, in mol dm, of H(aq) in A.
[H] in A
2(b)(ii)Weak Acids Bases BuffersMedium1 mark
Calculate the value of of CHCHCHCOOH at 298 K.
of CHCHCHCOOH
2(c)(i)Weak Acids Bases BuffersHard3 marks
Solution B is 100 cm of an aqueous solution containing 0.450 mol dm CHCHCHCOOH. Solution C is 200 cm of an aqueous solution containing sodium butanoate, CHCHCHCOONa.
B is added to C to produce 300 cm of solution D. The concentration of H ions in D is mol dm.
Calculate the concentration of CHCHCHCOONa in C. (If you were unable to calculate an answer in part (b)(ii), use as the value of of CHCHCHCOOH. This is not the correct answer.)
[CHCHCHCOONa] in C
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2(c)(ii)Weak Acids Bases BuffersMedium1 mark
Write an equation for the reaction when HSO(aq) is added to D.

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2(c)(iii)Weak Acids Bases BuffersMedium1 mark
Write an equation for the reaction when KOH(aq) is added to D.

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2(d)Carboxylic Acids EstersMedium2 marks
Predict the relative acidities of 2,2-dichlorobutanoic acid, CHCHCClCOOH, and butanoic acid, CHCHCHCOOH. Explain your answer.

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