May/June 2026 Paper 11

2026 · 40 questions · 40 parts · 40 marks

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33Aldehydes KetonesMedium1 mark
When an acidified aqueous solution of potassium cyanide is added to propanone, an addition reaction takes place. Which structure shows the intermediate formed during this reaction?
Structure A: in square brackets, a central carbon bonded to two CH3 groups and to a CN group, carrying a positive charge (+) beneath the central carbon, i.e. (CH3)2C(+)-CN, with no oxygen present.
Structure B: in square brackets, a central carbon bonded to two CH3 groups and to an OH group, carrying a positive charge (+) beneath the central carbon, i.e. (CH3)2C(+)-OH, with no CN present.
Structure C: in square brackets, a central carbon bonded to two CH3 groups, to an O atom drawn with no charge shown, and to a CN group carrying a negative charge (CN-) below the central carbon.
Structure D: in square brackets, a central carbon bonded to two CH3 groups, to an O atom carrying a negative charge (O-), and to a neutral CN group, i.e. (CH3)2C(O-)(CN), the alkoxide intermediate.