May/June 2026 Paper 23

2026 · 5 questions · 32 parts · 60 marks

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3(a)Enthalpy Changes Energy Profiles CalorimetryMedium2 marks
The conditions used for the conversion of sulfur dioxide to sulfur trioxide in the Contact process are carefully controlled.
Complete Figure 3.1 to show the reaction pathway diagram for reaction 1. Draw arrows to represent the enthalpy change, , and activation energy, .
Diagram to annotate
PenEraserUndoRedoClear
Draw with the mouse or a finger.
3(b)Dynamic Equilibria Equilibrium ConstantsEasy2 marks
Define Le Chatelier's principle.

Answer

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3(c)Dynamic Equilibria Equilibrium ConstantsHard3 marks
In industry, reaction 1 occurs at and with a catalyst.
Complete Table 3.1 by using the terms 'increase', 'decrease' or 'no change' for each condition.
effect on value of equilibrium constant,
effect on yield of product at equilibrium
effect on rate of reaction
3(d)(i)Dynamic Equilibria Equilibrium ConstantsMedium3 marks
A sealed tube that initially contains only of and of is left to reach equilibrium.
At equilibrium, of is present and the total pressure is .
Complete Table 3.2.
Table 3.2
amount initially / mol2.002.000
amount at equilibrium / mol1.96
mole fraction at equilibrium0.013250.3377
RowResponse
amount of at equilibrium / mol
amount of at equilibrium / mol
mole fraction of at equilibrium
3(d)(ii)Dynamic Equilibria Equilibrium ConstantsHard3 marks
Table 3.3 shows the mole fractions at equilibrium of , and under different conditions.
Table 3.3
mole fraction at equilibrium0.3600.0190.621
Calculate at using the data from Table 3.3. Include units in your answer.
Working, value and units
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