February/March 2026 Paper 42

2026 · 10 questions · 49 parts · 100 marks

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5(a)Gas Laws Kinetic TheoryMedium1 mark
State what is represented by the Avogadro constant.
5(b)Gas Laws Kinetic TheoryMedium3 marks
A gas is in a sealed container that has a fixed volume. The thermodynamic temperature of the gas is varied. Figure 5.1 shows how the pressure of the gas varies with , where is the number of molecules of the gas. Figure 5.2 shows how the mean-square speed of the molecules of the gas varies with . Figure 5.3 shows how the total kinetic energy of all the molecules of the gas varies with .
Figure 5.1, a graph of pressure $p$ (in $10^{4}\text{ Pa}$) against $NT$ (in $10^{26}\text{ K}$), a straight line through the origin rising to about $(8, 2.4)$
Figure 5.2, a graph of mean-square speed $\langle c^{2}\rangle$ (in $10^{6}\text{ m}^{2}\text{ s}^{-2}$) against thermodynamic temperature $T$ (in K), a straight line through the origin passing through $(200, 1.25)$ and reaching $(400, 2.50)$
Figure 5.3, a graph of total kinetic energy $E_{\text{K}}$ (in $10^{4}\text{ J}$) against thermodynamic temperature $T$ (in K), a straight line through the origin reaching about $(400, 1.3)$
Determine three conclusions about the gas that can be drawn from Figure 5.1, Figure 5.2 and Figure 5.3. The conclusions may be qualitative or quantitative.

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5(c)(i)Gas Laws Kinetic TheoryEasy1 mark
One assumption of the kinetic theory of gases is that the volume of the molecules is negligible compared with the volume of the gas. State, with a reason, whether this assumption applies to the gas in 5(b).

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5(c)(ii)Gas Laws Kinetic TheoryEasy2 marks
State two other assumptions of the kinetic theory of gases.

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